From: Subject: APPENDIX C Date: Wed, 24 Feb 2010 15:20:39 -0700 MIME-Version: 1.0 Content-Type: text/html; charset="Windows-1252" Content-Transfer-Encoding: quoted-printable Content-Location: http://silvercreekpc.accountsupport.com/RODtablesfiguresappendices.htm X-MimeOLE: Produced By Microsoft MimeOLE V6.00.2900.5579 APPENDIX = C
APPENDIX = C
 
RESPONSIVENESS SUMMARY

 

1.1  = Stakeholder Issues and EPA=20 Responses

 

During the=20 Public Comment Period for the Proposed Plan, comments were received from = UPCM,=20 the Marsac Corridor Association and Utah Department of Fish and = Wildlife.  Their comments and EPA=92s = response to=20 these comments are in the following sections.

 

1.1.2 Comments Received From = United=20 Park=20 City=20 Mines

Remedy = Selection. =20 United Park supports the remedy selected in the Proposed = Plan.  Like EPA, United = Park believes that Alternative 3 = provides=20 more than adequate protection of human health and the environment, will = prove to=20 be effective (both in the long and short terms), will be cost-effective, = and=20 will otherwise address the remaining environmental conditions necessary = to=20 achieve final closure of the Site. =20

Possible Wetlands Operable=20 Unit.  The Proposed Plan states that = the timing=20 of remediation as to the small wetland area between the impoundment and = Silver=20 Creek will be delayed until upstream remediation and reclamation efforts = are=20 complete.  United Park=92s = understanding is that the wetland area will be remediated following = remediation=20 of several upstream areas, some of which are located on United = Park property.  In any event, because the = timing for the=20 remediation of the wetland area will not be linked to the remediation = process=20 for the remainder of the Site, United Park suggests that EPA consider=20 designating the wetland area as a separate operable unit.  EPA has the discretion to = designate=20 multiple operable units with respect to the Site.  Doing so here makes sense in = part because=20 it will facilitate negotiation of the anticipated Consent Decree, = enabling EPA=20 and United=20 Park to define = construction=20 completion as to each operable unit.

EPA Response: =  While EPA understands this is = an option=20 that would allow the Site to be archived by OU more quickly, EPA feels = strongly=20 that the timing of cleanup throughout the Watershed will work to = everyone=92s=20 advantage.  By cleaning up = the=20 upstream sites along Silver Creek in a time efficient manner, the Site = wetlands=20 can then be excavated according to the plan set forth in this ROD.  It is critical to EPA that the = entire=20 Silver Creek Watershed be addressed and by further dividing sites by OU = or=20 through some other approach, EPA believes this will slow the process = down rather=20 that expedite it.

Site Impacts on Silver=20 Creek.  There are a number of = statements in the=20 Proposed Plan suggesting that the Site is presently having a significant = impact=20 on water quality in Silver Creek. =20 See page A-2 (first = paragraph)=20 (linking Site to other sites that are all impacting Silver Creek); page = A-3 and=20 A-4 (remediation of Site will play direct role in watershed = remediation).  United Park finds these = statements=20 confusing.  The Remedial=20 Investigation (=93RI=94) for the Site determined that surface waters = leaving the=20 Site present no significant impact on water quality in Silver = Creek.  While it is true that surface = waters in=20 areas upstream of the south diversion ditch exhibit elevated metal=20 concentrations, the water in the south diversion ditch outfall has = consistently=20 met surface water quality standards. =20 The remedial action proposed for the Site is more appropriately = described=20 at addressing potential = future=20 impacts the Site may have on Silver Creek. =20 While United = Park recognizes that many of the issues = addressing=20 Silver Creek arose generally from historic mining operations, United = Park believes it is = inappropriate to group=20 the Site with other areas in the Silver Creek Watershed that may have = actual=20 present impacts on water quality in Silver Creek. 

EPA Response: =20 EPA recognizes that the data from the Remedial Investigation = relating to=20 the Site=92s impact on Silver Creek support this statement.  It was written in the Proposed = Plan that=20 historic mining activities throughout the Upper Silver Creek Watershed = have=20 adversely affected Silver Creek.  = In=20 Section 12, The Selected Remedy, and in Section 5, Summary of Site=20 Characteristics, it is made clear that water from the Site that enters = Silver=20 Creek is of better quality than Silver Creek itself.   It is accurate to state = that the=20 selected remedy will be protective of human health and the environment = in that=20 it will minimize any future exposures or impacts contamination at the = Site may=20 present.

Human and Ecological=20 Risks.  United Park believes that the = Proposed=20 Plan mischaracterizes the results and findings of the human health and=20 ecological risk assessments relating to the Site.  More specifically, the = discussion in the=20 Proposed Plan under Human Health Risks (page A-4) states that "if the = necessary=20 cleanup action is not taken . . . there is a risk to future recreational = users=20 at the Site because of lead and arsenic present in the tailings."  In fact, the Baseline Human = Health Risk=20 Assessment ("BHHRA") conducted by EPA concluded no significant risk to=20 recreational users of the Site from the existing soils and mine tailings = unless=20 the soil cover is somehow disturbed. =20 With respect to the ecological risk assessment discussion, the = Proposed=20 Plan states that the Ecological Risk Assessment ("ERA") determined that=20 ecological receptors are potentially exposed to metals in several ways, = as=20 summarized in the chart on page A-4 of the Proposed Plan.  It would be more accurate to = state that=20 the ERA concluded contaminated sediment in the wetland area is the = primary=20 ecological risk driver, although surface water in a portion of the south = diversion ditch may also present some risk, to a lesser degree.  This conclusion is supported = by Table=20 7-8 in the ERA.

EPA Response: =20 Again, it is EPA=92s intent to make it clear that if the = necessary remedial=20 actions are not taken at the Site, which include both enhancing the soil = cover=20 and ensuring that it will remain intact in the future, potential risks = to human=20 health and the environment exist. =20 EPA agrees with the comment addressing sediments as the primary = risk=20 driver at the Site.

Future Consolidation of=20 Material.  United Park understands the = practical=20 benefits that could arise from the future use of the Site as a = consolidation=20 area for mining materials and impacted soils.  However, United = Park notes the potential = complications=20 related to defining completion of construction for purposes of the = remedial=20 action described in the Proposed Plan. =20 United Park suggests that one way to address this concern would = be for=20 EPA to provide in the ROD that:  = (i)=20 any materials so consolidated at the Site during implementation of the = remedial=20 action will simply be incorporated into the remedial action and covered = with the=20 required amount of  clean = cover=20 material and revegetated; and (ii) any material to be consolidated after = completion of construction will be subject to institutional controls = requiring=20 that mine wastes or impacted soils consolidated at the Site after the = remedial=20 action is completed would be covered with the required amount of  clean material and = revegetated.  This will allow United = Park to achieve a state of = completion with=20 the remediation while providing maximum flexibility for the future = consolidation=20 of material from the Watershed and any potential reuse of the=20 property.

EPA = Response: =20 EPA agrees with this comment; evidence of incoorporation of this = comment=20 into the ROD can be found in the Remedy Selection=20 section.

 

1.1.3 Comments=20 Received from the Marsac Corridor Association

 

One = component of=20 the remedy allows for waste to be transported from Empire = Canyon and deposited at = Richardson=20 Flat.  The Marsac Corridor = Association (MCA) is a group of homeowners that live in the neighborhood = through=20 which trucks carrying the waste would drive.  The members of the MCA had two = specific=20 comments: 1) The waste in Empire=20 Canyon should be left in = place, and 2)=20 If the waste must be moved, it should be transported up the Mine = Road and down=20 Royal=20 Street, rather than using only the = Mine = Road and=20 Lower Marsac.

 

EPA Response: EPA understands MCA=92s concerns = and has=20 considered its comments.  = It is our=20 perspective that the waste may be left in place or moved to Richardson = Flat.  Factors such as space to = contain the=20 waste, the cost of transportation, and potential migration of waste left = in=20 place will be considered by the parties involved in order to make a = decision=20 about the fate of the waste in Empire Canyon. EPA understands that = this is a=20 local issue and one that will be resolved through discussion and = consideration=20 amongst the stakeholders.  = These=20 stakeholders include Park City, UPCM, MCA and other = concerned=20 public.  A public hearing = will be=20 held by Park=20 City in the = upcoming future=20 to resolve this issue.  =

 

1.1.4 Comments=20 Received from United=20 States Fish and Wildlife Service (the = Service)=20 Utah Field Office

 

The = Service=20 submitted comments concerning the remedy=92s protectiveness in relation = to=20 ecological receptors at the Site. =20 The Service=92s primary concern is that the sediments found in = the South=20 Diversion Ditch, the pond at its terminus and in the wetland at the base = of the=20 embankment are not being addressed in a manner efficient enough to = substantially=20 minimize risk to ecological receptors at the site.  The Service proposes = excavation of the=20 sediments in all three areas.

 

EPA=20 Response:  The sediments within the = wetland area=20 will be excavated and placed within the impoundment through the selected = remedy.  EPA understands = that the=20 wetland is a naturally occuring ecological phenomenon that existed = before the=20 impoundment was created.  = Therefore,=20 the remedy should allow for the restoration of the wetland as a habitat = for=20 ecological receptors at the Site. =20 However, the diversion ditch and small pond are engineered = features at=20 the site that were constructed to help contain the tailings in the = impoundment=20 and minimize groundwater infiltration from Area B into the main=20 impoundment.  Therefore, = these areas=20 will be sufficiently remediated through the described mechanisms = (placement of=20 18 inches of gravel over contaminated sediments).  While this action does not = create=20 habitat or restore habitat, it will minimize risk to ecological = receptors at the=20 Site.  The requirements = set forth in=20 the NCP are met.  Lastly, = this does=20 not preclude continued negotiation concerning the restoration of these = features=20 between UPCM and EPA surrounding Natural Resource Damages.  These damages are currently = being=20 addressed, and they are a complicated issue.  It is possible these damages = could be=20 mitigated through the restoration of other areas within the = Watershed.  So, until a settlement = concerning these=20 damages has been reached the exposure pathways will be interrupted with = gravel=20 and risk to ecological receptors will be minimized in the diversion = ditch and=20 the pond at its terminus as it is described in the selected=20 remedy.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

APPENDIX=20 A

FIGURES FOR = THE RECORD=20 OF DECISION

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

APPENDIX=20 B

TABLES FOR THE = RECORD OF=20 DECISION

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Table 7-1

Summary of Chemicals of = Concern and=20

Medium-Specific Exposure = Point=20 Concentrations

 

Scenario=20 Timeframe:    =20 Current

Medium:           &nbs= p;            = ;=20            &n= bsp;           =20 Sediment

Exposure=20 Medium:        =20 Sediment

Exposure=20 Point

Chemical = of  Concern

Concentration=20 Detected

Units

Frequency = of=20 Detection

Exposure = Point=20 Concentration

Exposure = Point=20 Concentration Units

Statistical = Measure

Min

Max

Sediment:=20 Ingestion

Arsenic

101

310

mg/kg

12/12

200

mg/kg

95% = UCL

Lead

1,880

6,520

mg/kg

12/12

3,500

mg/kg

AM

Key:       =20

mg/kg: = milligrams per=20 kilogram

95% UCL: = 95% Upper=20 Confidence Limit of Arithmetic Mean

MAX: = Maximum=20 Concentration

AM:=20 Arithmetic Mean

 

 

 

 

 

 

 

Table=20 7-2

Summary of Chemicals of = Concern and=20

Medium-Specific Exposure = Point=20 Concentrations

 

Scenario = Time=20 frame:=20 Current

Medium:           &nbs= p;   =20 Surface Water

Exposure=20 Medium: Surface=20 Water

Exposure=20 Point

Chemical = of  Concern

Concentration=20 Detected

Units

Frequency = of=20 Detection

Exposure = Point=20 Concentration

Exposure = Point=20 Concentration Units

Statistical = Measure

Min

Max

Surface = Water -=20 Ingestion/ dermal exposure

Arsenic

0.025

0.75

mg/L

99/291

0.012

mg/L

95% = UCL

Lead

260

0.0015

mg/L

211/425

0.13

mg/L

AM

Key        =20

mg/L: = milligrams per=20 liter

95% UCL: = 95% Upper=20 Confidence Limit

MAX: = Maximum=20 Concentration

 

 

 

           &nbs= p;            = ;            =             &= nbsp;           &n= bsp;           &nb= sp;           &nbs= p;            = ;            =             &= nbsp;           &n= bsp;         =20

 

 

           &nbs= p;   =20

Table=20 7-3

Summary of Chemicals of = Concern and=20

Medium-Specific Exposure = Point=20 Concentrations

 

Scenario = Time=20 frame:=20 Current

Medium:           &nbs= p;   =20 Soil & Tailings

Exposure=20 Medium: Soil & = Tailings

Exposure=20 Point

Chemical = of  Concern

Concentration=20 Detected

Units

Frequency = of=20 Detection

Exposure = Point=20 Concentration

Exposure = Point=20 Concentration Units

Statistical = Measure

Min

Max

Soil&=20 Tailings:

Ingestion

Arsenic

2.5

2400

mg/kg

59/64

55

mg/kg

95% = UCL

Lead

14

5900

mg/kg

62/62

660

mg/kg

AM

Key        =20

mg/kg: = milligrams per=20 kilogram

95% UCL: = 95% Upper=20 Confidence Limit

AM: = Arithmetic=20 Mean

 

 

 

Table 7-4

Cancer Toxicity Data Summary

Pathway:=20 Ingestion

Chemical = of  Concern

Oral Cancer = Slope=20 Factor

Slope = Factor Units=20

Weight of=20 Evidence/Cancer Guideline Description

Source

Date

 

Arsenic

1.5

(mg/kg)/day

A

Region 3 = RBC=20 Table

8/28/2001

Lead

NA

NA

NA

NA

NA

KEY

EPA=20 Group:

A- Human=20 carcinogen

B1 = -Probable human=20 carcinogen - Indicates that limited human data are=20 available

B2 = -Probable human=20 carcinogen - Indicates sufficient evidence in animals and = inadequate or no=20 evidence in humans

C -Possible = human=20 carcinogen

D -Not = classifiable=20 as a human carcinogen

E -Evidence = of=20 noncarcinogenicity

 

RBC- Risk = Based=20 Concentration

NA: Not=20 Applicable

 

 

 

 

 

 

 

 

 

 

 

 

 

Table 7-5

Non-Cancer = Toxicity Data=20 Summary

Pathway:=20 Ingestion

Chemical=20 of  = Concern

Chronic/

Subchronic

Oral=20 RfD Value

Oral=20 RfD Units

 Dermal = RfD

Primary=20 Target Organ

Combined Uncertainty/

Modifying=20 Factors

Sources=20 of RfD:

Target=20 Organ

Dates=20 of RfD:

Target=20 Organ

 

Arsenic

Chronic

3.0E-04

mg/kg-day

=97

skin

=97

Region=20 3 RBC Table

 

8/28/01

Leada

=97

=97

=97

=97

=97

=97

=97

=97

Key

(1)=20 The dermal RfD was assumed to equal the oral RfD.  No adjustment factor was = applied

(2)=20 Toxicity values were pulled from the EPA Region 3 RBC=20 Table

 

a=20 There are no established criteria for lead; evaluation is made = using blood=20 lead levels

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Table=20 7-6

Risk Characterization Summary = =96=20 Carcinogens

 

Scenario=20 Timeframe:  =         =20 Future

Receptor=20 Population:  =         =20 Low Intensity Recreational User

Receptor = Age:         =            &n= bsp;    Child-Adult

Medium

Exposure=20 Medium

Exposure=20 Point

Chemical of = Concern

Carcinogenic=20 Risk

Ingestion

Inhalation

Dermal

Exposure = Routes=20 Total

Soil/Tailings

Soil/Tailings

Ingestion

 

Arsenic

 

2E-05

---

NE

2E-05

Dust

Inhalation

Arsenic

---

3.5E-10

NE

3.5E-10

Soil risk total=3D

2E-05

Sediment

Sediment

Ingestion

Arsenic

3E-06

---

NE

3E-06

 

Sediment Risk = Total=3D

3E-06

Surface=20 Water

Surface=20 Water

Ingestion

Arsenic

1.8E-07

NA

---

2.0E-07

Surface = Water Direct=20 Contact

Arsenic

---

NA

3E-08

3.0E-08

Surface = Water Risk=20 Total

4E-07

 

Total Risk =3D

2E-05

Key

NA:  Route of exposure is not = applicable to this medium.

NE:  Not evaluated=20

 

 

       =20

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

           &nbs= p;            = ;            =             &= nbsp;           &n= bsp;           &nb= sp;           &nbs= p;          =20

Table = 7-7

Risk Characterization = Summary =96=20 Carcinogens

 

Scenario=20 Timeframe:  =         =20 Future

Receptor=20 Population:  =         =20 High Intensity Recreational User

Receptor = Age:         =            &n= bsp;    Adult

Medium

Exposure=20 Medium

Exposure=20 Point

Chemical of = Concern

Carcinogenic=20 Risk

Ingestion

Inhalation

Dermal

Exposure = Routes=20 Total

Soil/Tailings

Soil/Tailings

Soil = On-site- Direct=20 Contact

 

Arsenic

 

1.1E-05

--

NE

1.1E-05

Dust

Soil = on-site=20 inhalation of soil as dust

Arsenic

--

6.1E-07

NE

6.1E-07

 

Total Risk=20 =3D

1.1E-05

Key

NE: Not=20 Evaluated

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Table = 7-8

Risk Characterization = Summary -=20 Non-Carcinogens

Scenario=20 Timeframe:  =         =20 Future

Receptor=20 Population:  =         =20 Low Intensity Recreational User

Receptor = Age:         =            &n= bsp;  Child-Adult

Medium

Exposure=20 Medium

Exposure=20 Point

Chemical of = Concern

Primary = Target=20 Organ

Non-Carcinogenic=20 Hazard Quotient

Ingestion

Inhalation

Dermal

Exposure = Routes=20 Total

Soil/=20 Tailings

Soil/=20 tailings

Ingestion

Arsenic

Liver

8.0E-02

N/A

---

8.0E-02

Dust

Inhalation

Arsenic

Liver

---

1.0E-07

---

1.0E-07

Soil/tailings Hazard Index = Total=20 =3D

8.0E-02

Sediment

Sediment

Ingestion

Arsenic

Liver

=97 =

=97 =

=97 =

1.0E-02

Sediment = Hazard Index=20 Total

1.0E-02

Surface=20 Water

Surface=20 Water

Ingestion

Arsenic

Liver

9.0E-04

N/A

----

9.0E-04

Dermal=20 contact

Arsenic

Liver

----

N/A

2.0E-04

2.0E-04

Surface = Water=20 Hazard  Index Total=20 =3D

1.1E-03

Total=20 Risk=3D

9.0E-02

Key

 

=97  :  Toxicity criteria are = not=20 available to quantitatively address this route of=20 exposure.

N/A:  Route of exposure is not = applicable to this medium.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Table = 7-9

Risk Characterization = Summary=20 =96Non-carcinogens

 

Scenario=20 Timeframe:  =         =20 Future

Receptor=20 Population:  =         =20 High Intensity Recreational User

Receptor = Age:         =            &n= bsp;  Adult

Medium

Exposure=20 Medium

Exposure=20 Point

Chemical of = Concern

Carcinogenic=20 Risk

Ingestion

Inhalation

Dermal

Exposure = Routes=20 Total

Soil/Tailings

Soil/Tailings

Ingestion

Arsenic

6.0E-02

--

NE

6.0E-02

Dust

Inhalation=20

Arsenic

--

3.0E-04

NE

3.0E-04

Total Risk=20 =3D

6.0E-02

Key

N/A:  Route of exposure is not = applicable to this medium. =

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Table = 7-10

Occurrence,=20 Distribution, and Selection of Chemicals of Concern=20 (COC)

 

Exposure=20 Medium: Surface = Water,=20 Dissolved (Aquatic Receptors)

 

Chemical of = Potential=20 Concern

 

Min=20 Conc.1

(ug/L)

 

Max=20 Conc.1

(ug/L)

 

Mean=20 Conc.

(ug/L)

 

95 % UCL of = the Mean=20 2

(ug/L)

 

Bkg=20 Conc.

(ug/L)

 

Screening = Toxicity=20 Value

(ug/L)

 

Screening = Toxicity=20 Value

Source=20 3

 

HQ Value=20 4

 

COC Flag=20

(Y/N)

 

Cadmium

 

1.0

 

46.3

 

4.3

 

5.2

 

N/A

 

0.22=20 5

 

NAWQC=20 Chronic

 

210

 

Y

 

Zinc

 

10

 

83,000

 

1,143

 

1,749

 

N/A

 

103=20 5

 

NAWQC=20 Chronic

 

806

 

Y

 

Key

Conc. =3D=20 Concentration

N/A =3D Not = Applicable

 

Notes

1 Minimum/ = maximum=20 detected concentration above the sample quantitation limit=20 (SQL).

2 The 95% = Upper=20 Confidence Limit (UCL) represents the RME=20 concentration.

3 NAWQC = Chronic =3D=20 USEPA National Ambient Water Quality Criteria for chronic=20 exposures.

4 Hazard = Quotient (HQ)=20 is defined as Maximum Concentration/ Screening Toxicity = Value.

5 Chronic = NAWQC value=20 is hardness-dependent; calculated based on the lowest measured = hardness in=20 site surface water samples (85 mg/L).

 

Table = 7-11

Occurrence,=20 Distribution, and Selection of Chemicals of Concern=20 (COC)

 

Exposure=20 Medium: Bulk = Sediment=20 (Benthic Invertebrates)

 

Chemical of = Potential=20 Concern

 

Min=20 Conc.1

(mg/kg)

 

Max=20 Conc.1

(mg/kg)

 

Mean=20 Conc.

(mg/kg)

 

95 % UCL of = the Mean=20 (mg/kg)

 

Bkg=20 Conc.

(mg/kg)

 

Screening = Toxicity=20 Value

(mg/kg)

 

Screening = Toxicity=20 Value

Source=20 3

 

HQ Value=20 4

 

COC Flag=20

(Y/N)

 

Cadmium

 

0.78

 

179

 

47.2

 

96.7

 

N/A

 

0.99

 

TEC

 

181

 

Y

 

Copper

 

20

 

2,559

 

440

 

681

 

N/A

 

32

 

TEC

 

80

 

Y

 

Mercury

 

0.05

 

6.2

 

1.5

 

2.9

 

N/A

 

0.18

 

TEC

 

34

 

Y

 

Nickel

 

9.0

 

97

 

25

 

29

 

N/A

 

23

 

TEC

 

4.2

 

N

 

Zinc

 

118

 

44,560

 

9,538

 

19,302

 

N/A

 

121

 

TEC

 

368

 

Y

 

Key

Conc. =3D=20 Concentration

N/A =3D Not = Applicable

 

Notes

1 Minimum/ = maximum=20 detected concentration above the sample quantitation limit=20 (SQL).

2 The 95% = Upper=20 Confidence Limit (UCL) represents the RME=20 concentration.

3 TEC =3D=20 Consensus-based Threshold Effect Concentration (MacDonald et al.,=20 2000)

4 Hazard = Quotient (HQ)=20 is defined as Maximum Concentration/ Screening Toxicity = Value.

 

 

 

 

 

 

Table = 7-12

Occurrence,=20 Distribution, and Selection of Chemicals of Concern=20 (COC)

 

Exposure=20 Medium: Sediment = Porewater,=20 Dissolved (Benthic organisms)

 

Chemical of = Potential=20 Concern

 

Min=20 Conc.1

(ug/L)

 

Max=20 Conc.1

(ug/L)

 

Mean=20 Conc.

(ug/L)

 

95 % UCL of = the Mean=20 2

(ug/L)

 

Bkg=20 Conc.

(ug/L)

 

Screening = Toxicity=20 Value

(ug/L)

 

Screening = Toxicity=20 Value

Source=20 3

 

HQ Value=20 4

 

COC Flag=20

(Y/N)

 

Arsenic

 

11

 

720

 

254

 

720=20 5

 

N/A

 

150

 

NAWQC=20 Chronic

 

4.8

 

Y

 

Zinc

 

230

 

2,700

 

1,310

 

2,700=20 5

 

N/A

 

342

 

NAWQC=20 Chronic

 

7.9

 

Y

 

Key

Conc. =3D=20 Concentration

N/A =3D Not = Applicable

 

Notes

1 Minimum/ = maximum=20 detected concentration above the sample quantitation limit=20 (SQL).

2 The 95% = Upper=20 Confidence Limit (UCL) represents the RME=20 concentration.

3 NAWQC = Chronic =3D=20 USEPA National Ambient Water Quality Criteria for chronic=20 exposures.

4 Hazard = Quotient (HQ)=20 is defined as Maximum Concentration/ Screening Toxicity = Value.

5 95UCL on = the mean is=20 greater than the maximum, maximum value is shown.

6 Chronic = NAWQC value=20 is hardness-dependent; calculated based on the lowest measured = hardness in=20 site sediment porewater samples (351 mg/L).

 

 

Table = 7-13

Occurrence,=20 Distribution, and Selection of Chemicals of Concern=20 (COC)

 

Exposure = Medium:=20 Sediment=20 (Waterfowl)

 

Chemical of = Potential=20 Concern

 

Min=20 Conc.1

(ppm)

 

Max=20 Conc.1

(ppm)

 

Mean=20 Conc.

(ppm)

 

95 % UCL of = the Mean=20 2

(ppm)

 

Bkg=20 Conc.

(ppm)

 

Screening = Toxicity=20 Value

(mg/kg/d)

 

Screening = Toxicity=20 Value

Source=20 3

 

HQ Value=20 4

 

COC Flag=20

(Y/N)

 

Lead

 

641

 

42,990

 

6,407

 

9,641

 

N/A

 

1.63

 

EcoSSL = Avian=20 TRV

 

93=20 5

 

Y

 

Key

Conc. =3D=20 Concentration

N/A =3D Not = Applicable

 

Notes

1 Minimum/ = maximum=20 detected concentration above the sample quantitation limit=20 (SQL).

2 The 95% = Upper=20 Confidence Limit (UCL) represents the RME=20 concentration.

3 Selected = Ecological=20 Soil Screening Level (EcoSSL) Toxicity Reference Value (TRV) for=20 birds.

4 Hazard = Quotient (HQ)=20 is defined as Maximum Concentration/ Screening Toxicity = Value.

5 Ingested = Dose from=20 sediment (mg/kg/d) calculated from maximum sediment concentration = using=20 exposure factors for the mallard duck.

 

 

 

 

 

 

 

Table = 7-14

Occurrence,=20 Distribution, and Selection of Chemicals of Concern=20 (COC)

 

Exposure=20 Medium: = Soil/Tailings=20 (Plants, Soil Invertebrates)

 

Chemical of = Potential=20 Concern

 

Min=20 Conc.1

(ppm)

 

Max=20 Conc.1

(ppm)

 

Mean=20 Conc.

(ppm)

 

95 % UCL of = the Mean=20 2

(ppm)

 

Mean Bkg=20 Conc.

(ppm)

 

Screening = Toxicity=20 Value

(ppm)

 

Screening = Toxicity=20 Value

Source=20 3

 

HQ Value=20 4

 

COC Flag=20

(Y/N)

 

Aluminum

 

813

 

32,700

 

10,662

 

18,066

 

N/A

 

50

 

Plant=20 SSL

 

654

 

Y

 

Lead

 

13

 

31,600

 

1,666

 

3,206

 

42

 

50

 

Plant=20 SSL

 

632

 

Y

 

Mercury

 

0.11

 

85

 

5

 

7.3

 

0.08

 

0.1

 

Invert.=20 SSL

 

850

 

Y

 

Zinc

 

47

 

33,800

 

4,085

 

15,255

 

104

 

50

 

Plant=20 SSL

 

676

 

Y

 

Key

Conc. =3D=20 Concentration

N/A =3D Not = Applicable

 

Notes

1 Minimum/ = maximum=20 detected concentration above the sample quantitation limit=20 (SQL).

2 The 95% = Upper=20 Confidence Limit (UCL) represents the RME=20 concentration.

3 Soil = Screening Level=20 (SSL), lowest of plant SSL or soil invertebrate = SSL.

4 Hazard = Quotient (HQ)=20 is defined as Maximum Concentration/ Screening Toxicity = Value.

 

Table=20 7-15

Ecological = Exposure=20 Pathways of Concern

 

Exposure=20 Medium

 

Sensitive = Environment=20 Flag

(Y or=20 N)

 

Receptor

 

Endangered/

Threatened = Species=20 Flag

(Y or=20 N)

 

Exposure=20 Routes

 

Assessment=20 Endpoints

 

Measurement = Endpoints

 

Sediment/Sediment=20 porewater

 

N

 

Benthic=20 organisms  =20

 

N

 

Ingestion = and direct=20 contact with chemicals in sediment

 

Protection = of aquatic=20 invertebrates and fish from adverse effects related to exposure to = chemicals in surface water and sediment

 

=B7   =20 Comparison = of=20 sampling location-specific chemical concentrations in sediment to = benthic=20 macroinvertebrate toxicity benchmarks.

=B7   =20 Comparison = of=20 sampling location-specific chemical concentrations in sediment = porewater=20 to benthic macroinvertebrate toxicity = benchmarks.

=B7   =20 Evaluate = the toxicity=20 of site sediment to Hyalella azteca (growth and survival) = through=20 laboratory testing.

 

Surface=20 Water

 

N

 

Fish

 

N

 

Ingestion = and direct=20 contact with chemicals in surface water

 

=B7   =20 Comparison = of=20 sampling location specific chemical concentrations in surface = water to=20 National Ambient Water Quality = Criteria.

 

Soil/Tailings

 

N

 

soil=20 invertebrates

 

N

 

Ingestion = and direct=20 contact with chemicals in wetland soils

 

Survival of = terrestrial invertebrate community

 

=B7   =20 Comparison = of=20 sampling location specific chemical concentrations in soil to = terrestrial=20 toxicity benchmarks

 

 

Terrestrial = plants

 

N

 

Uptake of = chemicals=20 via root systems

 

Maintenance/enhancement=20 of native site vegetation

 

Dietary=20 Intake

 

N

 

Wildlife = (birds and=20 mammals)

 

N

 

ingestion = of food=20 chain items

 

Protection = of=20 wildlife from adverse effects to growth, reproduction, or survival = related=20 to exposure to chemicals in surface water, sediment, and aquatic = food=20 items.

 

=B7   =20 Comparison = of=20 reach-specific chemical doses estimated from exposure point = concentrations=20 (EPCs) in surface water, sediment, and aquatic food items to = toxicity=20 reference values (TRVs) for=20 wildlife.

 

 

 

 

 

 

 

 

Table=20 7-16

Summary of = Uncertainties

 

Assessment = Component

 

Description

 

Likely = Direction=20

of=20 Error

 

Likely = Magnitude=20

of=20 Error

 

Nature and = Extent of=20 Contamination

 

Samples = collected=20 may not be fully representative of variability in space or time,=20 especially if the number of samples is = small.

 

Unknown

 

Probably=20 small

 

Analytical = results=20 may be imprecise.

 

Unknown

 

Probably=20 small

 

Exposure=20 Assessment

 

Some = exposure=20 pathways were not evaluated.

 

Underestimate of=20 risk

 

Probably=20 small

 

Some = chemicals were=20 not evaluated because chemical was never detected, but detection = limit was=20 too high to detect the chemical if it were present at a level of=20 concern.

 

Underestimate of=20 risk

 

Usually=20 small

 

Exposure = parameters=20 for wildlife receptors are based on studies at other=20 sites.

 

Unknown

 

Probably=20 small

 

Exposure = point=20 concentrations for wildlife receptors are based on a conservative = estimate=20 of the mean concentration in the exposure area. =

 

Overestimate of=20 risks

 

Possibly=20 significant

 

Absorption = from site=20 media is assumed to be the same as in laboratory=20 studies.

 

Overestimate of=20 risks

 

Possibly=20 significant

 

Toxicity=20 Assessment

 

Many = chemicals lack=20 reliable toxicity benchmarks for some receptors for some = media;  these chemicals are not=20 evaluated.

 

Underestimation of=20 risk

 

Probably = small in=20 most cases

 

Available = toxicity=20 benchmarks are often based on limited data, and values must be=20 extrapolated across species.

 

Unknown

 

Unknown, = could be=20 significant

 

Wildlife = receptors=20 selected as representative species may not capture the full range = of=20 sensitivities in site receptors.

 

Unknown

 

Probably=20 small

 

Aquatic = toxicity=20 benchmarks are based on a wide range of species, some of which do = not=20 occur at this site.

 

Likely to=20 overestimate risk

 

Probably=20 small

 

Risk=20 Characterization

 

Interactions between=20 chemicals are difficult to account for;  effects of one chemical = may=20 increase, decrease, or have no effect on other=20 chemicals.

 

Unknown

 

Unknown, = but=20 probably small

 

Estimation = of=20 population-level effects from HQ calculations is difficult and = subject to=20 professional judgement.

 

Unknown

 

Unknown, = probably=20 small in most = cases